Donwilhelmsite : New mineral from the moon could explain what happens in the Earth’s mantle

The new mineral donwilhelmsite is the first high-pressure mineral found in meteorites.

Fragments of the Oued Awlitis 001 meteorites acquired by the Ludovic-Ferrière. Credit: University of Manchester
Fragments of the Oued Awlitis 001 meteorites acquired by the Ludovic-Ferrière. Credit: University of Manchester

A team of European researchers discovered a new high-pressure mineral in a lunar meteorite which is helping to explain what happens to materials within the extreme pressures of the Earth’s mantle.

The new mineral donwilhelmsite is the first high-pressure mineral found in meteorites with application for terrestrial sediments dragged deep into the Earth mantle by plate tectonics. Mainly composed of calcium, aluminum, silicon, and oxygen atoms, donwilhelmsite was discovered within the lunar meteorite Oued Awlitis 001 found in 2014 in the Western Sahara.

The meteorite is compositionally similar to rocks comprising the Earth’s continents. Eroded sediments from these continents are transported by wind and rivers to the oceans, and subducted into the Earth’s mantle as part of the dense oceanic crust. Once dragged to depths of about 460-700 km, their constituent minerals transform at high pressures and high temperatures existing at those depths into denser mineral phases, including the newly discovered mineral donwilhelmsite. In the terrestrial rock cycle, donwilhelmsite is therefore an important agent for transporting continental crustal sediments through the transition zone of the Earth’s mantle (460-700 km depth).

Around 382 kilograms of rocks and soils have been collected by the Apollo and Luna missions, lunar meteorites allow valuable insights into the formation and evolution of the moon. Ejected by impacts onto the lunar surface and subsequently delivered to Earth, some of these meteorites experienced particularly high temperatures and pressures.

Dr. Vera Assis Fernandes of The University of Manchester measured the Argon isotopic composition of lunar rocks to date their complex history including magmatic formation, multiple impact bombardments, and the exposure to cosmic rays on the lunar surface, over billions of years. Dr. Fernandes explains: “During impact bombardment rocks like the lunar meteorite Oued Awlitis 001 experience extreme physical conditions. This often led to shock melting of microscopic areas forming veins or melt pockets within these meteorites.

Recommended For You  How Earth's Pacific plates collapsed

“These shocked areas are of great relevance as they mirror pressure and temperature regimes similar to those prevailing in the Earth’s mantle, and therefore are natural crucibles hosting minerals that are otherwise naturally inaccessible at the Earth’s surface.”

The new discovery is published in the journal American Mineralogist.

Mariana Klementova applied the cutting edge 3-D electron diffraction (3DED) technique, together with a specially developed software to solve, for the first time, the crystal structure of an extraterrestrial mineral. Dr. Vera Assis Fernandes determined the ages of various events in the complex history of this meteorite, including the formation of the new mineral donwilhlemsite. The new mineral was named in honor of the lunar geologist Don E. Wilhelms, an American scientist involved in landing site selection and data analyses of the Apollo space missions that brought to Earth the first rock samples from the moon. Part of the meteorite Oued Awlitis 001 is now on display at the Natural History Museum Vienna.

Reference:
Jörg Fritz et al. Donwilhelmsite, [CaAl4Si2O11], a new lunar high-pressure Ca-Al-silicate with relevance for subducted terrestrial sediments, American Mineralogist (2020). DOI: 10.2138/am-2020-7393

Note: The above post is reprinted from materials provided by University of Manchester.